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We have determined the intramolecular potential barrier as well as total activation energies of trans‐cis isomerization in the excited state of stilbene in hydrocarbons, using UV picosecond transient‐absorption Spectroscopy. The dynamics of the isomerization is compared with theoretical predictions offered by the activated barrier crossing models of Kramers, and Grote and Hynes.
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Sundström et al. (1985) studied this question.
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