A new organic–inorganic hybrid, (TTF+)FeIII(C2O4)Cl2, displaying canted antiferromagnetism has been prepared and characterized, where the tetrathiafulvalene (TTF) molecules are face-to-face dimers and the anion is a one-dimensional coordination polymer (see Figure). Due to π–d interactions through short S…Cl and S…O contacts a three-dimensional Néel state is stabilized at the high temperature of 20 K.
No takes yet. Share an insight, caveat, or question.
Zhang et al. (2005) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: