The optical emission spectrum of the methylnitrene radical has been observed at a resolution of 0.07 cm−1. Transitions to subbands with K up to 3 in the X̃ 3A2 ground state were observed and a full rotational analysis carried out. Comparison of the structural information with the highest level theoretical calculations shows agreement to within the estimated error.
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Brazier et al. (1992) studied this question.
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