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November 14, 2002Angewandte Chemie International Edition

Organically Templated Mixed-Valent Iron Sulfates Possessing Kagomé and Other Types of Layered Networks

Geo Paul Amitava Choudhury E. V. Sampathkumaran C. N. R. Rao

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Abstract

A perfect Kagomé lattice is displayed by the mixed-valent layered structure of [HN(CH2)6NH][FeIIIFeF6(SO4)2]⋅[H3O] (see picture), in which 100 % of the iron sites are occupied. The complex exhibits unusual magnetic properties; both magnetic frustration and ferrimagnetic behavior are observed.

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Paul et al. (2002) studied this question.

synapsesocial.com/papers/6a97c523618eaafe842d3200 https://doi.org/10.1002/1521-3773(20021115)41:22<4297::aid-anie4297>3.0.co;2-e

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