The reaction between the isopolyanion [Mo7O24]6– and the bivalent transition-metal ions Mn2+, Co2+, and Cu2+ has been studied spectrophotometrically. It is suggested that 1 : 1 complexes are formed in solution. The probable formulation and ligand-field spectra of the 1 : 1 complexes are discussed. The formation constants of the complexes are small, 260–1 000 dm3 mol–1.
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Malik et al. (1977) studied this question.