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Redox reactions in the initial products formed from K2[Cr(CO)5] and Cl2ER (E = Al, Ga; R = Cl, alkyl) lead to the formation of aluminum(I) and gallium(I) transition metal complexes of type 1 (shown below) that are surprisingly stable. Stoichiometric CrGa films were prepared from 1 (E = Ga, R = CH2CH3) by MOCVD. tmeda = N,N,N′,N′,‐tetramethylethylenediamine. equation image
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Schulte et al. (1996) studied this question.
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