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When the Br80m in HBr80m undergoes isomeric transition the HBr80 bond is broken in 93% or more of the events rather than only 75% as indicated by earlier work. In gaseous mixtures of HBr, CH3Br, and 1,2-dibromethylene containing either HBr80m or CH3Br80m, the distribution of the Br80 daughter between organic and inorganic combination is dependent upon the HBr/C2H2Br2 ratio, indicating that C2H2Br2 does not compete as effectively with HBr for the Br80 atoms as formerly thought.
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Luebbe et al. (1958) studied this question.
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