Hydrogen Bond Studies. 62. The Crystal Structure of a High Temperature Modification of Dimethylammonium Chloride (CH3)2NH2Cl: an X-Ray and Infrared Study.

Jan Lindgren; Nükhet Arran; Arne F. Andresen; M. J. Tricker; Sigfrid Svensson

doi:10.3891/acta.chem.scand.26-3043

January 1, 1972Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistryOpen Access

Hydrogen Bond Studies. 62. The Crystal Structure of a High Temperature Modification of Dimethylammonium Chloride (CH3)2NH2Cl: an X-Ray and Infrared Study.

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Key Points

To resolve the high-temperature crystal structure and characterize hydrogen bonding patterns in dimethylammonium chloride.
Examined single-crystal samples of the high-temperature modification using X-ray diffraction techniques.
Collected infrared spectra to investigate vibrational modes and hydrogen bond interactions between dimethylammonium cations and chloride anions.
Determined the crystallographic symmetry, unit cell parameters, and atomic coordinates of the high-temperature phase.
Identified N–H···Cl hydrogen bonding networks that stabilize the reorganized high-temperature molecular crystal lattice.

Implication

Structural analysis reveals the crystal geometry and hydrogen bonding in high-temperature dimethylammonium chloride, highlighting temperature-dependent molecular rearrangements.

Discussion

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Lindgren et al. (1972) studied this question.

synapsesocial.com/papers/6a97f54780327c22c38be103 https://doi.org/10.3891/acta.chem.scand.26-3043

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Hydrogen Bond Studies. 62. The Crystal Structure of a High Temperature Modification of Dimethylammonium Chloride (CH3)2NH2Cl: an X-Ray and Infrared Study.

Key Points

Implication

Discussion

Cite This Study

Hydrogen Bond Studies. 62. The Crystal Structure of a High Temperature Modification of Dimethylammonium Chloride (CH3)2NH2Cl: an X-Ray and Infrared Study.

Key Points

Implication

Discussion

Cite This Study

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