Formation Process of Pt Subnano-Clusters on Graphene Nanosheets

The formation mechanism of Pt subnano-clusters composed of 5–40 Pt atoms on graphene nanosheets (GNS) has been studied by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscope (TEM). The exchange of Cl – ion by OH – ion and the reduction of Pt 4+ to Pt 2+ are examined by XPS in the reduction of an H 2 PtCl 6 catalyst precursor by ethanol at different pH. XPS and TEM results show that particles of Pt 2+ -containing compounds with the sizes of 2–7 nm are first formed on GNS by the reduction of H 2 PtCl 6 with ethanol, which are then fully reduced to Pt subnano-clusters by H 2 at 400 °C. The proposed mechanism for the Pt subnano-cluster formation includes two pivotal surface reactions: the reduction of Pt 2+ particles into isolated Pt atoms by H 2 on the GNS surface, followed by the formation of Pt subnano-clusters by collision of the Pt single atom migrating on GNS.