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The momentum distributions of annihilating positron–electron pairs have been measured in liquid and solid methane. Calculated momentum distributions generally assume that the positron wave function ψ+ = 1. This low-momentum, plane-wave representation of the positron is inadequate to describe the experimental distribution for high momenta. A ψ+ obtained by numerical integration of the ground-state radial Schrödinger equation is employed in the calculation and a good fit is observed with experiment for all momentum values.
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Chuang et al. (1968) studied this question.
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