Photocatalytic self-cleaning textile fibers have been created using coaxial electrospinning. This is accomplished by electrospinning cellulose acetate as the core phase and a dispersion of nanocrystalline TiO 2, a well-known photocatalyst, in the sheath phase. A simple deacetylation step after the initial electrospinning yields self-cleaning textile fibers. Self-cleaning activity is exhibited at moderate power densities in indoor lighting conditions. Nanofibers created from coaxial electrospinning outperform TiO 2 surface-loaded nanofibers obtained by conventional electrospinning. Surface-loaded fibers degrade blue dye stains only to a minimum of 20% of the initial concentration, whereas fibers created by coaxial electrospinning fully degrade stains (in 7−8 h).
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Bedford et al. (2010) studied this question.
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