A trinuclear palladium(II) chloride phosphane complex, [(PdCl2)3(PAr3)2], is obtained in the reaction of a bowl-shaped triarylphosphane with a deep cavity with PdCl2 even when an excess amount of the phosphane is employed. X-ray crystallography established the structure of the complex: a trimer of PdCl2 is terminated by two phosphane ligands (see picture).
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Ohzu et al. (2003) studied this question.
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