The Ru atom in the title compound, [Ru(C6H5CN)2{P(C6H5)3}{C6H4(NH)2}(H2O)](BF4)2·H2O, has six-coordinate octahedral geometry, with a trans arrangement of the triphenylphosphine ligand and the water molecule. The asymmetric unit contains one complex cation, two tetrafluoroborate anions and one solvent water molecule, which is disordered over two sites (ratio of occupancies 0.70:0.30).
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Venegas‐Yazigi et al. (2000) studied this question.
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