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The electronic structure of chemisorbed layers on metal surfaces is studied for general coverages. The Anderson model of chemisorption investigated by Newns is used and the CPA method for the random alloy is applied to obtain the Green function of the chemisorbed layer. The state density, the charge on the adatom and the heat of adsorption are calculated as functions of coverage. As a typical example in which the electron correlation is important, H/W(100) system is investigated.
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Masaru Tsukada (1976) studied this question.
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