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Abstract 2,3‐Dihydro‐1,3‐diisopropyl‐4,5‐dimethylimidazol‐2‐ylidene 1 (Carb, R1 = iPr, R2 = Me) reacts with TeI4 to give the carbene adduct CarbTeI2 (3). The crystal structure of 3 consists of T‐shaped monomeric fragments linked by weak Te. I interactions to form infinite helical chains.
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Kühn et al. (2005) studied this question.
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