The reactions of ketene silyl acetals and silyl enol ethers in a CCl4 solution containing no promoter under ambient temperature, reflux, or photo-irradiation conditions afforded products via the addition of a trichloromethyl group to those silyl substrates. Polyhalides other than CCl4 were subjected to photoreactions in a hexane solution, resulting in the formation of carbonyl derivatives based on the addition of polyhalogenated alkyl groups.
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Mitani et al. (2002) studied this question.
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