An alkylperoxo complex of Mn(II) bearing a highly hindered alkyl-substituted tris(pyrazolyl)borate ligand, TpBut,PriMnII(OOCMe2Ph) (TpBut,Pri = hydrotris(3-tert-butyl-5-iso-propylpyrazolyl)borate), has been synthesized by dehydrative condensation of a corresponding mononuclear Mn(II) hydroxo complex TpBut,PriMnII(OH), with cumyl hydroperoxide. X-ray crystallography shows that the divalent manganese center of the alkylperoxo complex adopts an essentially tetrahedral geometry with a N3O ligand donor set.
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Komatsuzaki et al. (1998) studied this question.
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