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The synthesis and characterization of the new six- and seven-membered Pd–PEPPSI-type N-heterocyclic carbene (NHC) complexes 3 and 4 is described. Complexes of the general formula [Pd(NHC)(3ClPy)Cl 2 ] (NHC = 6- or 7-Mes, 3ClPy = 3-chloropyridine) are accessed via the oxidation of the well-defined parent palladium(0) complexes 1 and 2 . Complexes 3 and 4 have been employed in Suzuki–Miyaura cross-coupling and catalytic dehalogenation of a range of aryl halide substrates.
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Dunsford et al. (2014) studied this question.
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