Gallium(III)-substituted P-450 models, [Ga(OEP)(SAr)] (OEP=octaethylporphinato; SAr=S-2-CF3CONHC6H4, SPh), were synthesized and the structures were determined by X-ray analysis. The gallium(III) complexes were found to be excellent structural analogues having a diamagnetic metal center.
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Okamura et al. (1998) studied this question.
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