Two novel palladium catalysed cascade processes involving the generation of a (π-allyl)palladium intermediate from allenes in an intra- or intermolecular fashion, followed by regioselective intramolecular nucleophilic addition of amines, alcohols or malonates provide spiro- or linear fused heterocycles in good yield.
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Grigg et al. (2001) studied this question.
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