Two viscometric methods in the investigation of interpolymer complexes are presented. It has been shown that a presentation of the reduced viscosity ratio (experimental to ideal value) of a mixture of a polyacid with a nonionic polymer at constant total concentration as a function of the polymer mixture composition gives a better insight into the interpolymer association than a presentation of the specific viscosity at constant polyacid concentration as a function of the unit molar ratio. The formation of an expanded structure interpolymer complex is more easily revealed by the former procedure.
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Staikos et al. (1993) studied this question.
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