All articles of this category A facile synthesis of aryl vinylphosphonates has been based on Heck reaction of aryldiazonium salts bearing electrowithdrawing or donating groups with vinylphosphonates. A one-pot procedure consisting of Heck reaction and hydrogenation permits the clean formation of useful Wadsworth-Emmons reagents. Heck reaction - palladium - arenediazonium salts - hydrogenation - vinylphosphonates - Wadsworth-Emmons reactives
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Brunner et al. (2000) studied this question.