A kinetic compensation effect was observed for acid‐catalyzed hydrolysis of a series of disaccharides. Twelve data sets for acid hydrolysis of three disaccharides reported in the literature were analyzed and compensation parameters were determined. The results are well described by following empirical compensation expression: In k o = AE a + B with A = 1.241 and B = ‐2.317. The isokinetic temperature calculated from this compensation relationship was 132.4°C which was located beyond experimental temperature ranges.
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Rhim et al. (1989) studied this question.
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