Sowing the seeds: Complexation of rac-1 in the solid state with a guest such as Et2O in the gas phase proceeds in the presence of a seed crystal of the inclusion complex (see scheme). For example, passing Et2O over a mixture of 1 and a seed of 1⋅(Et2O)3 gives rise to exclusive formation of the 1:3 complex.
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Yoshizawa et al. (2005) studied this question.
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