The dinuclear iron(II) complex {[Fe(CH3bipy)(NCS)2]2bpym} has been synthesised and its crystal structure determined at 293 K. The magnetic properties display intramolecular antiferromagnetic coupling at 1 bar (J = −4.2 cm−1), and the onset of a pressure‐induced spin conversion is observed at 11 kbar. Magnetic field Mössbauer measurements have been carried out at 4.2 K, and indicate that the HS species correspond to [HS‐HS] pairs. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
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Gaspar et al. (2004) studied this question.
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