A six-membered Co2O4 ring in a chair conformation is featured in the diamagnetic dimer 2, which is in equilibrium with its CoII monomer 1 (ΔH = -14.5(5) kcalmol−1 and ΔS = -60(3) cal (K−1 mol−1). The dimerization of 1 and loss of O2 from 2 are steps en route to dioxygen activation. Tp′ = hydrotris(3-isopropyl-5-methylpyrazolyl)borate).
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Reinaud et al. (1995) studied this question.
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