High lithium ionic conductivity is exhibited by an organic–inorganic hybrid electrolyte prepared by self-assembly of a PEO-PPO-PEO triblock copolymer (Pluronic F127; PEO=poly(ethylene oxide), PPO=poly(propylene oxide)), complexed with LiClO4, on a silica framework. The good performance of the hybrid material with an [O]:[Li] ratio of 16:1 is due to its well-ordered mesophase consisting of a hexagonal arrangement of cylinders (see diagram).
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Kao et al. (2004) studied this question.
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