A microwave-assisted protocol furnished cinnamic acid esters from electron-deficient olefins at 120 °C using 1,3-bis(diphenylphosphino)propane (dppp) as the supporting ligand and para-benzoquinone (p-BQ) as the hydride acceptor. Use of acetone as the solvent and methanol as a co-solvent, the electron-rich olefin, n-butyl vinyl ether, was regioselectively arylated to furnish branched products under the same conditions.
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Sävmarker et al. (2012) studied this question.
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