New strategy: A novel phosphine-catalyzed domino reaction of activated conjugated dienes and electron-deficient olefins was developed. In this reaction, intermolecular Rauhut–Currier reaction was successfully incorporated in a domino process, and a variety of highly functionalized cyclopentenes were obtained in good yields and diastereoselectivities. Two new CC bonds were formed together with a quaternary carbon center.
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Hu et al. (2012) studied this question.
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