For the alkaloids meloscine, epimeloscine and scandine, isolated from the Apocynacee Melodinus scandens FORST., the structures 1, 10 and 11, respectively, are deduced. Scandine is proved to possess the relative configuration as shown in 11 r. For meloscine and epimeloscine the relative configurations as depicted in 1 r and 10 r are discussed.
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Bernauer et al. (1969) studied this question.