Synthetic model polypeptides containing phosphorylated amino acid residues are an important class of materials for proving the mechanism of biomineralization. In previous studies, we synthesized (i) homopolypeptides [1] and random copolypeptides [2] containing O-phospho-L-serine [Ser(PO3H2)] and aspartic acid that characteristically exist in organic matrix proteins related to
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Hayashi et al. (2006) studied this question.
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