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We present a simple, general method for calculating the binding energies of excitons in quantum-confined structures. The binding energy is given by an integral (over the electron and hole coordinates perpendicular to the confining layers) of a prescribed function weighted by the squares of the electron and hole subband envelope functions. As a test of the method, we calculate the binding energies for heavy- and light-hole excitons in a rectangular GaAs/Al0.3{Ga}0.7$As quantum well as functions of the well width. Very good agreement with previous results is obtained over a wide range of quantum-well widths. Also, we determine the binding energies for heavy-hole excitons as functions of electric field in a GaAs/Al0.35{Ga}0.65$As asymmetric coupled-quantum-well structure. Our results compare favorably with those obtained in a treatment in which coupling of the electron subbands via the electron-hole Coulomb interaction is considered. Our method should be applicable to a variety of complex quantum-confined semiconductor structures for which more rigorous approaches require extensive numerical calculations.
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Leavitt et al. (1990) studied this question.
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