1-Aminoalkylphosphinates 4 have been obtained in good yields in a one-step transformation by the Mitsunobu reaction of 1-hydroxyalkylphosphinates 1 with hydrazoic acid, and subsequent treatment of the intermediate azides 2, with triphenylphosphine, followed by hydrolysis of the iminophosphoranes 3 with water.
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Tadeusz Gajda (1993) studied this question.
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