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The polymerization reactions of isoprene with the use of H2O2 as the photoinitiator have been studied in acetone solutions. The lifetime of chain radicals, τs, was evaluated to be 0.29 by the rotating sector technique. The rate constants kp and kt were found to be 19.1 and 3.40 × 107 L/mol‐ s, respectively.
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Chang et al. (1985) studied this question.
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