Nickel sulfide nanorods decorated on graphene as advanced hydrogen evolution electrocatalysts in acidic and alkaline media

Nowadays, the fabrication of robust and earth-abundant hydrogen evolution electrocatalysts with noble-metal-like catalytic activities is still facing great challenges. In this report, nanorod (NR)-shaped nickel sulfide (NiS) is successfully decorated on graphene (Gr) by utilizing carbon cloth (CC) as a substrate (NiS-Gr-CC). Benefiting from the NR morphology and strong interfacial synergetic effect between NiS and Gr, the NiS-Gr-CC electrocatalyst shows good catalytic activity for hydrogen evolution reaction (HER). Specifically, the low Tafel slopes of 46 and 56 mV dec -1 along with the small overpotentials of 66 and 71 mV at 10 mA cm −2 are obtained in the acidic and alkaline electrolytes, respectively. Density functional theory results indicate that the combination of NiS and Gr can optimize the adsorption energy of H* during the HER process. The long-term durability measurement result reveals that our NiS-Gr-CC heterostructure has good electrocatalytic cycling stability (∼80 h) in both acidic and alkaline electrolytes. These results confirm that the NiS-Gr-CC heterostructure is a promising candidate for hydrogen evolution electrocatalyst with high catalytic activity.