Resonance Raman spectroscopy was utilized for the first time to characterize the nature of the 1 metal‐to‐ligand charge transfer (MLCT) state of a ruthenium complex containing the redoxactive tetraazatetrapyrido‐pentacene (tatpp) ligand. The presented results show that the long‐wavelength absorption is originating from transitions involving the terminal phenanthroline and the tatpp ligands.
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Tschierlei et al. (2008) studied this question.
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