The copolymerization of styrene and 4-methoxystyrene by constant potential electrolysis in 1,2-dichloroethane was achieved at three different potentials. Amounts of the monomers in the resulting copolymers were found to be potential-dependent. The effect of polymerization potential on copolymer composition was also found to be related to anodic peak potentials (Ep,a) of the monomers. Monomer reactivity ratios were found with the integrated Lewis-Mayo equation.
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Toppare et al. (1984) studied this question.
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