A study of the ESR spectra of several β-diketone chelate complexes of copper(II) in the frozen solution of toluene has revealed that triplet-state dimers are formed at high concentrations in the solution and that these dimers are in equilibrium with only the monomers. The approximate equilibrium constants have been determined by a careful analysis of the ESR spectra observed in various concentrations. Structures for the dimers have been suggested from magnetic parameters properly determined using a point dipole model.
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Yokoi et al. (1973) studied this question.
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