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The metallic mercury solubility in hydrocarbons (pentane, hexane, heptane, and octane) was determined in the temperature range from 5 to 40 °C by the cold-vapor atomic absorption method. The results, for pentane at 25 °C, were found to agree well with Kuntz’s result obtained by means of the ultraviolet absorption method, while those for hexane, heptane, and octane were found to agree well with Spencer’s results, which were obtained using a radioactivetracer technique in the above temperature range. The liquid-liquid distribution constant for metallic mercury between the above hydrocarbons and water was measured at 25 °C, and in each case was found to be equal to the ratio of the independent solubility in the hydrocarbon and in water.
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Okouchi et al. (1981) studied this question.
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