The formation ofN‐chlorobutylamines is a reaction of order one with respect to hypochlorite and amine, and order −1 with respect to OH−. Kinetic studies show thatN‐chlorobutylamines undergo decomposition in basic aqueous media, and disproportination (with formation ofN,N‐dichloramines) in acidic media, mechanisms are put forward for both these processes.
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Antelo et al. (1995) studied this question.
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