The effective Debye temperature of poly(vinylidene fluoride-trifluoroethylene) copolymers was measured using photoemission and neutron diffraction techniques. An effective Debye temperature of 53±11 K is obtained from the photoemission data and 69±3.5 K from neutron diffraction measurements. This effective Debye temperature is a consequence of the temperature-dependent dynamic motions perpendicular to the surface of these crystalline polymer films.
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Borca et al. (1999) studied this question.
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