Pyramidal silicon centers within the SiC bond are the most prominent feature of the first cyclic silenes stable at room temperature, as exhibited by X-ray diffraction (see structure) and calculations. They are quantitatively formed by reaction of lithium disilenides, disila analogues of vinyllithium compounds, with acid chlorides, and are relatively inert, for example, towards the addition of MeOH.
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Bejan et al. (2007) studied this question.
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