Effect of Dopants on Zirconia Stabilization—An X‐ray Absorption Study: I, Trivalent Dopants

Local atomic structures of Zr and dopant cations in zirconia solid solutions with Fe 2 O 3 , Ga 2 O 3 , Y 2 O 3 , and Gd 2 O 3 have been determined. The Zr ions in both partially stabilized tetragonal and fully stabilized cubic zirconia have their own characteristic structures which are dopant‐independent. The dopant cations substitute for Zr ions despite severe local distortions necessitated by the large difference in dopant–O distance ana Zr─O distance. Dopant ionic size determines the preferred locations of oxygen vacancies. Vacancies introduced by oversized dopants (Y and Gd) are located as nearest neighbors to Zr atoms, leaving 8‐fold oxygen coordination to dopant cations. Undersized dopants (Fe and Ga) compete with Zr ions for the oxygen vacancies in zirconia, resulting in 6‐fold oxygen coordination and a large disturbance to the surrounding next nearest neighbors. Since oxygen vacancies associated with Zr can provide stability for tetragonal and cubic zirconia, these results suggest an explanation for the observation that oversized trivalent dopants are more effective than undersized trivalent dopants in stabilizing cubic and tetragonal phases.