The behavior of adsorbed CO and reaction intermediates on Rh/SiO2has been observed at high pressure CO hydrogenation condition by in situ FT-IR spectroscopy. A good relationship exists between turnover frequency of CO conversion and the ratio of bridged-CO/linear-CO adsorbed on Rh/SiO2 at the reaction condition in terms of Rh dispersion of catalysts. Turnover frequency increases with the increase of this ratio as a general trend. Two kinds of acetate species as reaction products on SiO2 have been observed.
No takes yet. Share an insight, caveat, or question.
Arakawa et al. (1985) studied this question.
Synapse has enriched 5 related papers. Consider them for comparative context: