Surface-initiated Kumada catalyst-transfer polycondensation of poly(9,9-dioctylfluorene) (PFO) was performed from organosilica microparticles that resulted in PFO brushes with densely grafted PFO chains with a significantly enhanced propensity to adopt planar and ordered conformations (beta-phase).
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Tkachov et al. (2009) studied this question.
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