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The preparation of an electron-deficient (N−N)PtCl 2 complex in which the diimine C is substituted by CF 3 is described. Thus, reactions between the diimine ligand 1 (R = CF 3, R‘ = 2,6-dimethylphenyl) and PtCl 2 (thermal reaction) or KPtCl 3 (C 2 H 4 ) (photochemically activated) furnishes the corresponding (N−N)PtCl 2 complex 2 . The ligand 1 and its Pt complexes 2, as well as related (N−N)PtCl 2 complexes 3 (R = CO 2 CD 3, R‘ = 2,6-dimethylphenyl; a methanolysis product) and 4 (R = H, R‘ = 2,6-dimethylphenyl) have been characterized by X-ray crystallography.
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Lersch et al. (2007) studied this question.
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