Triethylenetetramine (trien) cobalt(III) complexes with 1,2-ethanedithiolate (edt) or 1,2-ethanedisulfinate (edsi) were prepared and characterized by absorption, CD, and 13C NMR spectra. Each of the two complexes gave three possible geometrical isomers (cis-α, cis-β-RR,SS, and cis-β-RS,SR) which were separated and optically resolved by fractional crystallization and/or column chromatography.
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Konno et al. (1989) studied this question.
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