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November 28, 2011Polymer Chemistry

Grignard metathesis (GRIM) polymerization for the synthesis of conjugated block copolymers containing regioregular poly(3-hexylthiophene)

Mihaela C. Stefan Mahesh P. Bhatt Prakash Sista Harsha D. Magurudeniya

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Abstract

The synthesis of various conjugated block copolymers of regioregular poly(3-hexylthiophene) by Grignard metathesis (GRIM) polymerization is described.

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Cite This Study

Stefan et al. (2011) studied this question.

synapsesocial.com/papers/6a99b9c119f97c1d5a844da3 https://doi.org/10.1039/c1py00453k

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Highly conducting, soluble, and environmentally-stable poly(3-alkylthiophenes)Original Research · 1986 · 350 citations
2Enhanced electrical conductivity in regioselectively synthesized poly(3-alkylthiophenes)Original Research · 1992 · 577 citations
3Design, synthesis, and control of conducting polymer architectures: structurally homogeneous poly(3-alkylthiophenes)Original Research · 1993 · 905 citations
4Chain Growth Mechanism for Regioregular Nickel-Initiated Cross-Coupling PolymerizationsOriginal Research · 2004 · 532 citations
5The first regioregular head-to-tail poly(3-hexylthiophene-2,5-diyl) and a regiorandom isopolymer: nickel versus palladium catalysis of 2(5)-bromo-5(2)-(bromozincio)-3-hexylthiophene polymerizationOriginal Research · 1992 · 527 citations

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Regiocontrolled Synthesis of Poly(3-alkylthiophenes) Mediated by Rieke Zinc: Their Characterization and Solid-State Properties1995
A Simple Method to Prepare Head-to-Tail Coupled, Regioregular Poly(3-alkylthiophenes) Using Grignard Metathesis1999
Regioregular, Head-to-Tail Coupled Poly(3-alkylthiophenes) Made Easy by the GRIM Method: Investigation of the Reaction and the Origin of Regioselectivity2001

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