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The displacements of double bonds by basic catalysts (N‐lithioethylene diamine with an excess of ethylene diamine, potassiumt‐butylate in dimethylsulfoxide, benzyl‐sodium in boiling xylene) are studied onp‐menthenes andp‐menthadienes. The isomerizations ofp‐menthadienes are accompanied by dehydrogenation. A representative mechanism of isomerization and dehydrogenation according to the catalyst is proposed for limonene.
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Ferro et al. (1974) studied this question.
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