Coordinated control: Owing to their numerous synthetic challenges, polytellurophenes are a virtually unexplored class of conjugated polymers. A new dihalogenated bitellurophene monomer has been synthesized and its polymerization under palladium-catalyzed conditions was optimized. The resulting polytellurophenes are stable compounds with distinct optoelectronic properties that can be controlled by coordination with bromine (see picture).
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Jahnke et al. (2010) studied this question.
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